HANDLING
ACID SOLUTIONS
#1 PROCESS
Mixing various concentrations of aqueous
acid solutions.
#2 HAZARDOUS CHEMICALS/CLASS OF HAZARDOUS
CHEMICALS
Acids - nitric, sulfuric, hydrochloric,
acetic, phosphoric
#3 PERSONAL PROTECTIVE EQUIPMENT
Safety goggles, nitrile, PVC, or neoprene
gloves. Avoid skin contact, serious burns may result. Gloves made of nitrile,
neoprene, or PVC can provide effective skin protection. Wear safety glasses
or chemical safety goggles with face shield when using large quantities,
or chemical safety goggles when using small quantities. Wear rubber, neoprene,
or PVC apron when using large quantities and splash potential exists.
#4 ENGINEERING/VENTILATION CONTROLS
Use concentrated acids in fume hood. A
safety shower and eyewash must be available and accessible when working
with corrosive liquids.
#5 SPECIAL HANDLING PROCEDURES AND STORAGE
REQUIREMENTS
Store mineral acids together, separate
from oxidizing agents and organic materials. Store containers of acids
and bases separately in chemical resistant secondary containers. This could
be a polyethylene, PYREX or Nalgene tray or pan.
ACID & CORROSIVE CABINETS
Bottles of acid should be stored in an
acid (corrosive) cabinet. While
acids and bases are both considered to
be corrosive, care must be taken to not
store acids and bases in the same cabinet.
It is particularly important to
avoid storing ammonium hydroxide and strong
mineral acids in the same cabinet.
Oxidizing acids, such as fuming nitric,
fuming sulfuric and nitric should
be stored separately, in a secondary container
within an acid cabinet.
Polypropylene boxes for use in acid cabinets
are available commercially.
Glacial acetic acid, although it is both
a corrosive and flammable, should be
stored with other, non-oxidizing acids
away from those mentioned above, not in a flammables cabinet.
#6 SPILL AND ACCIDENT PROCEDURES
Skin exposure: Rinse affected skin
with plenty of water while removing contaminated clothing and shoes. Rinse
for at least 15 minutes. Seek medical attention.
Eye exposure: Splashes may cause
tissue destruction. Wash eyes for at least 15 minutes, lifting the upper
and lower eyelids occasionally. Seek medical attention immediately.
Small spills: Do not attempt cleanup
if you feel unsure of your ability to do so or if you perceive the risk
to be greater than normal laboratory operations. Cover spill with sodium
carbonate or bicarbonate. When reaction stops pickup with damp sponge or
paper towels.
Large Spills: Notify others in area
of spill. Turn off ignition sources in area. Evacuate area and post doors
to spill area. Call EH&S:
* Office of Environmental Health &
Safety 292-1284
* University Police 911 This is
a 24 hour service.
Remain on the scene, but at a safe
distance, to receive and direct safety personnel when they arrive.
Restrict persons from area of spill or leak until cleanup is complete.
Remain in area in safe location to assist EH&S with response.
#7 WASTE DISPOSAL
Dispose of waste through EH&S.
#8 SPECIAL APPROVAL REQUIRED
NO
#9 DECONTAMINATION
Use sodium bicarbonate and water.
#10 DESIGNATED AREA
NO |