PROCTER & GAMBLE -- DAWN LIQUID DISHWASHING DETERGENT MATERIAL SAFETY DATA SHEET NSN: 793000N018770 Manufacturer's CAGE: 74188 Part No. Indicator: A Part Number/Trade Name: DAWN LIQUID DISHWASHING DETERGENT =========================================================================== General Information =========================================================================== Company's Name: PROCTER & GAMBLE Company's Street: 301 E SIXTH ST Company's P. O. Box: 599 Company's City: CINCINNATI Company's State: OH Company's Country: US Company's Zip Code: 45201 Company's Emerg Ph #: 800-543-0485 Company's Info Ph #: 800-543-0485 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 002 Status: SMJ Date MSDS Prepared: 26JUL88 Safety Data Review Date: 17APR95 MSDS Serial Number: BLFYH Hazard Characteristic Code: F4 =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: ETHYL ALCOHOL (ETHANOL) Ingredient Sequence Number: 01 NIOSH (RTECS) Number: KQ6300000 CAS Number: 64-17-5 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM; 9192 =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: CLEAR BLUE LIQUID. PRODUCT IS PERFUMED. Specific Gravity: 1.03 Solubility In Water: COMPLETELY SOLUBLE Percent Volatiles By Volume: 60 =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: 116F,47C Flash Point Method: CC Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: CO*2, WATER, OR DRY CHEMICAL. Special Fire Fighting Proc: ALTHOUGH THIS PRODUCT HAS A FLASH PT BELOW 200F (CLOSED CUP), IT IS AN AQUEOUS SOLUTION CONTAINING ETHYL ALCOHOL WHICH DOES NOT SUSTAIN COMBUSTION.(SUPP DATA) Unusual Fire And Expl Hazrds: NONE. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): NONE KNOWN. Materials To Avoid: CHLORINE BLEACH. Hazardous Decomp Products: NONE KNOWN. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: NO Route Of Entry - Skin: NO Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: EYE: MAY CAUSE MILD TRANSIENT IRRITATION. INGEST: MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION. SKIN: TRANSIENT IRRITATION W/PROLONGED EXPOSURE TO CONCENTRATED MATERIAL. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: EYE: MAY CAUSE STINGING, TEARING, ITCHING, SWELLING, &/OR REDNESS. INGEST: MAY RESULT IN NAUSEA, VOMITING, &/OR DIARRHEA. SKIN: PROLONGED CONTACT W/CONCENTRATED MATERIAL MAY BE DRYING. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYE: FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES. INGEST: DRINK 1 OR 2 GLASSES OF WATER. SKIN: IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY W/WATER. IF SPILLED ON CLOTHING, CHANGE CLOTHES. IF SYMPTOMS PERSIST OR REOCCUR, SEEK MEDICAL ATTN. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) (FP N). =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: FLUSH DOWN ACCEPTABLE SEWER (CONTAINS BIODEGRADABLE SURFACTANTS). PREVENT LARGE SPILLS FROM REACHING A WATERWAY. SORBENTS MAY BE USED. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE W/ FEDERAL, STATE, & LOCAL REGULATIONS. SMALL OR HOUSEHOLD QUANTITIES MAY BE DIPOSED OF IN SEWER. FOR LARGER QUANTITIES, INCINERATION IS PREFERRED. DO NOT LANDFILL. Precautions-Handling/Storing: NO UNUSUAL PRECAUTIONS NECESSARY. Other Precautions: CONSUMER PRODUCT PACKAGE HAS NO CAUTION STATEMENT. DO NOT MIX WITH CHLORINE BLEACH AS HAZARDOUS FUMES MAY RESULT. =========================================================================== Control Measures =========================================================================== Respiratory Protection: NONE REQUIRED WITH NORMAL USE. IF NECESSARY, USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE. Protective Gloves: NONE REQUIRED W/NORMAL USE. (SUPP DATA) Eye Protection: NONE REQUIRED W/NORMAL USE. (SUPP DATA) Other Protective Equipment: NONE NECESSARY UNDER NORMAL USE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: FIRE FIGHT PROC: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). PROT GLOVES: RUBBER, NEOPRENE GLOVES SHOULD BE USED FOR PROLONGED DIRECT CONTACT. EYE PROT: IF A SPLASH IS LIKELY, CHEMICAL WORKERS GOGGLES MAY BE NEEDED. =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 91339 DOT PSN Code: GJL DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. DOT Class: 3 DOT ID Number: UN1993 DOT Pack Group: III DOT Label: FLAMMABLE LIQUID IMO PSN Code: HIA IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMO Regulations Page Number: 3345 IMO UN Number: 1993 IMO UN Class: 3.3 IMO Subsidiary Risk Label: - IATA PSN Code: MCA IATA UN ID Number: 1993 IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. * IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID AFI PSN Code: MCA AFI Prop. Shipping Name: FLAMMABLE LIQUIDS, N.O.S. AFI Class: 3 AFI ID Number: UN1993 AFI Pack Group: III AFI Basic Pac Ref: 7-7 =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: P Technical Review Date: 23SEP91 Label Date: 23SEP91 Label Status: G Common Name: DAWN LIQUID DISHWASHING DETERGENT Chronic Hazard: NO Signal Word: CAUTION! Acute Health Hazard-Slight: X Contact Hazard-Slight: X Fire Hazard-Slight: X Reactivity Hazard-Slight: X Special Hazard Precautions: ACUTE: MAY CAUSE MILD TRANSIENT EYE AND SKIN IRRITATION. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. DO NOT MIX WITH CHLORINE BLEACH, AS HAZARDOUS FUMES MAY RESULT. CHRONIC: NONE LISTED BY MANUFACTURER. Protect Eye: Y Protect Skin: Y Label Name: PROCTER & GAMBLE Label Street: 301 E SIXTH ST Label P.O. Box: 599 Label City: CINCINNATI Label State: OH Label Zip Code: 45201 Label Country: US Label Emergency Number: 800-543-0485