ASHLAND CHEMICAL -- ETHANOL SDA 3A 200 PROOF
MATERIAL SAFETY DATA SHEET
NSN: 681000D005104
Manufacturer's CAGE: 34897
Part No. Indicator: A
Part Number/Trade Name: ETHANOL SDA 3A 200 PROOF
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                            General Information
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Item Name: (NO TIR/CTDF)
Company's Name: ASHLAND CHEMICAL COMPANY
Company's P. O. Box: 2219
Company's City: COLUMBUS
Company's State: OH
Company's Country: US
Company's Zip Code: 43216-2219
Company's Emerg Ph #: 800-274-5236 0R 800-ASHLAND
Company's Info Ph #: 614-889-3333
Distributor/Vendor # 1: AMERICAN DRUG INDUSTRIES
Distributor/Vendor # 1 Cage: 0SU46
Distributor/Vendor # 2: FREY SCIENTIFIC
Distributor/Vendor # 2 Cage: 6U218
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SE
Date MSDS Prepared: 22DEC88
Safety Data Review Date: 25JUN96
Preparer's Company: (DATA SHEET #:0020122-002)
MSDS Serial Number: BZNFB
Specification Number: UNKNOWN
Hazard Characteristic Code: F3
Unit Of Issue: NK
Unit Of Issue Container Qty: UNKNOWN
Type Of Container: UNKNOWN
Net Unit Weight: UNKNOWN
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                     Ingredients/Identity Information
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Proprietary: NO
Ingredient: ETHYL ALCOHOL (ETHANOL)
Ingredient Sequence Number: 01
Percent: 95
NIOSH (RTECS) Number: KQ6300000
CAS Number: 64-17-5
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM; 9495
Other Recommended Limit: NONE RECOMMENDED
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Proprietary: NO
Ingredient: METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
Ingredient Sequence Number: 02
Percent: 5
NIOSH (RTECS) Number: PC1400000
CAS Number: 67-56-1
OSHA PEL: S, 200 PPM
ACGIH TLV: S,200PPM/250STEL; 95
Other Recommended Limit: NONE RECOMMENDED
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                     Physical/Chemical Characteristics
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Appearance And Odor: ALCOHOL.
Boiling Point: 171F,77C
Vapor Pressure (MM Hg/70 F): 48.50 @68F
Vapor Density (Air=1): 1.5
Specific Gravity: 0.794 @60F
Evaporation Rate And Ref: 2.67 (N-BUTYL ACETATE=1)
Percent Volatiles By Volume: 100
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                      Fire and Explosion Hazard Data
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Flash Point: 60.0F,15.6C
Flash Point Method: TOC
Lower Explosive Limit: 3.3
Extinguishing Media: ALCOHOL FOAM OR WATER FOG OR CARBON DIOXIDE OR DRY
CHEMICAL.
Special Fire Fighting Proc: WERAR SELF-CONTAINED BREATHING APPARATUS W/
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING
FIRES.
Unusual Fire And Expl Hazrds: VAP HEAVIER THANT AIR;MAY RAVEL ALONG
GROUND/MOVE BY VENTI/IGN BY PILOT LIGHTS/OTHER FLMES/SPAKRS/IGN SOURCES
@LOCATIONS DISTANT FRM MATL HNDLG PT.(SUPPLEMENT)
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                              Reactivity Data
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Stability: YES
Cond To Avoid (Stability): AVOID ALL SOURCES OF IGNITION.
Materials To Avoid: AVOID CONTACT W/STRONG OXIDIZING AGENTS.
Hazardous Decomp Products: MAY FORM TOXIC MATLS, CARBON DIOXIDE, CARON
MONOXIDE, ETC.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT APPLICABLE
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                            Health Hazard Data
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LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: NO
Health Haz Acute And Chronic: EYE:SEVERE IRRIT,REDNESS,TEARING,BLURRED
VISION.SKIN:PROLONGED/REPEAT CONTACT CAN CAUSE MODERATE IRRIT,DEFATTING,
DERM.BREATH:EXCESSIVE VAP INHAL CAN CAUSE NASAL/RESP IRRIT,CNS EFFECTS,
POSSIBLE UNCONSC,DEATH.SWALLOW:CAUSE GASTROINTESTINAL IRRIT,NAU,VOMIT,
DIARR,BLINDNESS,DEATH.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: PER MSDS:NO CARCINOGEN PRESENT.
Signs/Symptoms Of Overexp: OVEREXPO TO THIS MATL/COMPONENETS HAS BEEN
SUGGESTED AS CAUSE OF FOLLOWING EFFECTS IN HUMANS:LIVER ABNORMALITIES, EYE
DAMAGE. CNS EFFECTS:DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE,
POSSIBLE UNCONSC, DEATH.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: SKIN:THOROUGHLY WASH W/SOAP/WATER.REMOVE
CONTAMIN CLOTH.EYE:FLLUSH W/LG AMTS OF WATER LIFTING EYELIDS.GET MED ATTN.
INGEST:IMMED DRINK 2 GLASSES OF WATER.INDUCE VOMIT BY EITHER GIVING IPECAC
SYRUP OR BY PLACING FINGER @BACK OF THROAT.NEVER GIVE ANYTHING BY MOUTH IF
UNCONSC.GET MED ATTN IMMED.INHAL:REMOVE TO FRESH AIR.BREATH DIFF GIVE OXY.
STOP BREATH GIVE ART RESP.KEEP WARM/REST.GET MED ATTN.
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                   Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: ABSORB ON PAPER/VERMI/FLR ABSORBENT/OTHER
ABSORBENT MATL.TRANSF TO HOOD.ELIMINATE ALL IGN SOURCES.EXCLUDED THOSE NOT
W/PPE.STOP SPILL.DIKE/PUMP LIQ TO SALVAGE TK.REMAINING LIQ TAKE UP W/SAND,
CLAY,EARTH,FLR ABSORBENT,OTHER ABSORBENT.SHOVEL INTO CNTNR.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: SM:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD.
ALLOW SUFFI TIME FOR VAP TO CLEAN HOOD DUCT WORK.DISPOSE REMAINING MATL IAW
APPLIACABLE REGS.LG:DESTROY BY LIQ INCINERATION.CONTAMIN ABSORBENT MAY BE
DEPOSITED IN LANDFILL IAW LOC/STATE/FED REGS.
Precautions-Handling/Storing: CONTAINS METHANOL.CANNOT BE MADE NON-
POISONOUS.CNTNRS MAY BE HAZ WHEN EMPTIED SINCE THEY RETAIN PROD
RESIDUES(VAP/LIQ/SOL)FOLLOW ALL PRECAUT GIVEN.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
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                             Control Measures
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Respiratory Protection: WORKPLACE EXPO LIMITS OF PROD/INGRED EXCEEDED
NIOSH/MSHA APPROVED AIR-SUPPLIED RESP ADVISED IN ABSENCE OF PROPER ENVIRO
CNTRL.OSHA REGS PERMIT OTHER NIOSH/MSHA RESP UNDER SPEC CONDITION.ENGIN/ADM
CNTNRL SHOULD BE IMPLEMENTED TO REDUCE EXPO.
Ventilation: PROVIDE SUFFICIENT MECHANICAL(GEN &/OR LOC EXHAUST)
VENTILATION TO MAINTAIN EXPO BELOW TLVS.
Protective Gloves: RESISTANT GLOVES SUCH AS NEOPRENE.
Eye Protection: CHEM SPLASH GOGG,OTHER TYP SAF GLASSES.
Other Protective Equipment: TO PREVENT REPEATE/PROL SKIN CONTACT WEAR
IMPERV CLOTH & BOOTS.
Work Hygienic Practices: LAUNDER CONTAMIN CLOTH BEF REUSE. WASH HANDS AFT
HANDLING.
Suppl. Safety & Health Data: FIRE/EXPLO HAZ:NEVER WELD/VUT TORCH ON/NEAR
DRM(EVEN EMPTY)-PROD(EVEN JUST RESIDUE)CAN IGN EXPLO.ALL 5GAL PAILS/LGER
METAL CNTNR INCLUDING TK CAR/TK TRK SHOULD BE GROUNDED &/OR BONDED WHEN
MATL TRANSF.
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                            Transportation Data
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Trans Data Review Date:   96136
DOT PSN Code: FTN
DOT Proper Shipping Name: ETHANOL OR ETHYL ALCOHOL OR ETHANOL SOLUTIONS OR
ETHYL ALCOHOL SOLUTIONS
DOT Class: 3
DOT ID Number: UN1170
DOT Pack Group: II
DOT Label: FLAMMABLE LIQUID
IMO PSN Code: GOQ
IMO Proper Shipping Name: ETHANOL
IMO Regulations Page Number: 3219
IMO UN Number: 1170
IMO UN Class: 3.2
IMO Subsidiary Risk Label: -
IATA PSN Code: KXQ
IATA UN ID Number: 1170
IATA Proper Shipping Name: ETHANOL
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
AFI PSN Code: KXQ
AFI Prop. Shipping Name: ETHANOL OR ETHANOL SOLUTIONS OR ETHYL ALCOHOL OR
EHTYL ALCOHOL SOLUTIONS
AFI Class: 3
AFI ID Number: UN1170
AFI Pack Group: II
AFI Basic Pac Ref: A7.3
Additional Trans Data: PER MSDS:DOT HAZ CLASS:FLAMMABLE LIQUID.
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                               Disposal Data
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                                Label Data
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Label Required: YES
Technical Review Date: 25JUN96
Label Status: F
Common Name: ETHANOL SDA 3A 200 PROOF
Signal Word: DANGER!
Acute Health Hazard-Severe: X
Contact Hazard-Severe: X
Fire Hazard-Severe: X
Reactivity Hazard-None: X
PROLONGED/REPEAT CONTACT CAN CAUSE MODERATE IRRIT,DEFAT,DERM.BREATH:EXCESS
CAUSE GI IRRIT,NAU,VOMIT,DIARR,BLINDNESS,DEATH.CONTAINS METHANOL.CANNOT BE
MADE NON-POISONOUS.TARORG:EYE/SKIN/CNS/GI.1STAID:SKIN:WELL WASH W/SOAP/
IMMED DRINK 2 GLASSES OF WATER.INDUCE VOMIT BY GIVING IPECAC SYRUP OR PLACE
FINGER @BACK OF THROAT.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.INHAL:MOVE
TO FRESH AIR.BREATH DIFF GIVE OXY.STOP BREATH GIVE ART RESP.IN ALL CASES
GET MED ATTN.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: ASHLAND CHEMICAL COMPANY
Label P.O. Box: 2219
Label City: COLUMBUS
Label State: OH
Label Zip Code: 43216-2219
Label Country: US
Label Emergency Number: 800-274-5236 0R 800-ASHLAND
Year Procured: 1996