CAROLINA BIOGOLICAL SUPPLY -- ACETIC ACID, GLACIAL
MATERIAL SAFETY DATA SHEET
NSN: 675000D007013
Manufacturer's CAGE: 59896
Part No. Indicator: A
Part Number/Trade Name: ACETIC ACID, GLACIAL
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                            General Information
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Company's Name: CAROLINA BIOGOLICAL SUPPLY CO
Company's Street: 2700 YORK RD
Company's City: BURLINGTON
Company's State: NC
Company's Country: US
Company's Zip Code: 27215-3387
Company's Emerg Ph #: 800-227-1150/910-584-0381(OUT SIDE)
Company's Info Ph #: 800-227-1150/910-584-0381(OUT SIDE)
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SE
Date MSDS Prepared: 22JUL97
Safety Data Review Date: 12SEP97
Supply Item Manager: CX
MSDS Serial Number: CFKCJ
Hazard Characteristic Code: F6
Unit Of Issue Container Qty: 500 ML
Net Unit Weight: 1.15 LBS
NRC/State License Number: NOT RELEVANT
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                     Ingredients/Identity Information
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Proprietary: NO
Ingredient: ACETIC ACID (CERCLA)
Ingredient Sequence Number: 01
Percent: 100
NIOSH (RTECS) Number: AF1225000
CAS Number: 64-19-7
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM/15 STEL; 9596
Other Recommended Limit: NONE RECOMMENDED
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                     Physical/Chemical Characteristics
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Appearance And Odor: CLEAR, COLORLESS LIQUID; STRONGLY PUNGENT VINEGAR-
LIKE ODOR
Boiling Point: 244F,118C
Melting Point: 62.1F,16.7C
Vapor Pressure (MM Hg/70 F): 11.4 @ 68F
Vapor Density (Air=1): 2.07
Specific Gravity: 1.049
Decomposition Temperature: UNKNOWN
Evaporation Rate And Ref: 0.97 (N-BUTYL ACETATE=1)
Solubility In Water: COMPLETE
Percent Volatiles By Volume: 100
Corrosion Rate (IPY): UNKNOWN
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                      Fire and Explosion Hazard Data
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Flash Point: 109F,43C
Flash Point Method: CC
Extinguishing Media: DRY CHEMICAL (ABC), CARBON DIOXIDE, ALCOHOL FOAM. USE
WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Special Fire Fighting Proc: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. WATER IN A STRAIGHT HOSE STREAM WILL
SCATTER AND SPREAD FIRE.
Unusual Fire And Expl Hazrds: VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS
MAY RUPTURE. VAPOR FORMS EXPLOSIVE MIXTURE+AIR
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                              Reactivity Data
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Stability: YES
Cond To Avoid (Stability): EXCESSIVE HEAT, FREEZING, SPARKS, FLAMES AND
OTHER SOURCES OF IGNITION
Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES, METALS, AMINES,
OXIDES, XYLENE, COMBUSTIBLE MATERIALS
Hazardous Decomp Products: CARBON MONOXIDE, CARBON DIOXIDE, CORROSIVE
VAPORS MAY BE FORMED.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
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                            Health Hazard Data
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LD50-LC50 Mixture: LD50 (ORAL, RAT) IS 3530 MG/KG (RTECS).
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI
TRACTS. ACUTE- DANGER! CORROSIVE, POISON. INHALATION:VAPOR EXTREMELY
IRRITATING. MAY CAUSE DELAYED LUNG INJURY. EYES:CAUSES SEVERE BURNS. VAPORS
EXTREMELY IRRITATING. SKIN:CAUSES SEVERE BURNS. ORAL:MAY BE FATAL. MAY
CAUSE GASTROINTESTINAL TRACT BURNS. CHRONIC- UNKNOWN.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NONE
Signs/Symptoms Of Overexp: SEVERE IRRITATION, SEVERE BURNS, PAIN, TEARING,
COUGHING
Med Cond Aggravated By Exp: PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE
PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THIS PRODUCT.
REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH
WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. SKIN:IMMEDIATELY
FLUSH WITH WATER, THEN WATER CONTAINING SODIUM BICARBONATE. ORAL:DO NOT
INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER, FOLLOW WITH
MILK OF MAGNESIA, BEATEN EGGS OR VEGETABLE OIL.
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                   Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA.
REMOVE IGNITION SOURCES. NEUTRALIZE WITH BAKING SODA. ABSORB WITH
VERMICULITE. PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY. PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS OR STREAMS.
Neutralizing Agent: SODIUM BICARBONATE (BAKING SODA), SODA ASH
Waste Disposal Method: DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO
LOCAL, STATE AND FEDERAL REGULATIONS. NEUTRALIZE WITH SODIUM BICARBONATE
AND FLUSH TO SEWER WITH COPIOUS AMOUNT OF WATER, IF LOCAL ENVIRONMENTAL
REGULATIONS PERMIT.
Precautions-Handling/Storing: STORE IN VENTILATED AREA, AWAY FROM SOURCES
OF IGNITION & INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED AT
TEMPERATURES ABOVE 63F.
Other Precautions: CORROSIVE, FLAMMABLE. DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. AVOID INHALATION OF VAPORS. KEEP OUT OF REACH OF CHILDREN. OBEY
HAZARD WARNING LABEL. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD/HOUSEHOLD
USE. USE WITH ADEQUATE VENTILATION
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                             Control Measures
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Respiratory Protection: WORK IN VENTILATION HOOD OR WEAR A NIOSH-APPROVED
ACID GAS RESPIRATOR. A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE
WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation: LOCAL EXHAUST OR CHEMICAL HOOD
Protective Gloves: PVC
Eye Protection: SAFETY GLASSES WITH SIDE SHIELDS/GOGGLES
Other Protective Equipment: SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE
LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE.
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR.
Suppl. Safety & Health Data: NONE
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                            Transportation Data
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Trans Data Review Date:   97255
DOT PSN Code: AAT
DOT Proper Shipping Name: ACETIC ACID, GLACIAL OR ACETIC ACID SOLUTION,
DOT Class: 8
DOT ID Number: UN2789
DOT Pack Group: II
DOT Label: CORROSIVE, FLAMMABLE LIQUID
IMO PSN Code: ACF
IMO Proper Shipping Name: ACETIC ACID, GLACIAL
IMO Regulations Page Number: 8100
IMO UN Number: 2789
IMO UN Class: 8
IMO Subsidiary Risk Label: FLAMMABLE LIQUID
IATA PSN Code: ABL
IATA UN ID Number: 2789
IATA Proper Shipping Name: ACETIC ACID, GLACIAL
IATA UN Class: 8
IATA Subsidiary Risk Class: 3
IATA Label: CORROSIVE & FLAMMABLE LIQUID
AFI PSN Code: ABL
AFI Prop. Shipping Name: ACETIC ACID GLACIAL, OR ACETIC ACID SOLUTION
AFI Class: 8
AFI ID Number: UN2789
AFI Pack Group: II
AFI Label: CORROSIVE
AFI Special Prov: A7, A10
AFI Basic Pac Ref: A12.3
Additional Trans Data: NONE
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                               Disposal Data
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                                Label Data
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Label Required: YES
Technical Review Date: 12SEP97
Label Status: G
Common Name: ACETIC ACID, GLACIAL
Chronic Hazard: NO
Signal Word: WARNING!
Acute Health Hazard-Moderate: X
Contact Hazard-Severe: X
Fire Hazard-Severe: X
Reactivity Hazard-None: X
Special Hazard Precautions: WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA.
REMOVE IGNITION SOURCES. NEUTRALIZE WITH BAKING SODA. ABSORB WITH
VERMICULITE. PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY. PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS OR STREAMS. FIRST
AID: GET MEDICAL ATTENTION IMMEDIATELY. INHALED:REMOVE TO FRESH AIR.
PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER FOR AT
LEAST 15 MINUTES. HOLD EYELIDS OPEN. SKIN:IMMEDIATELY FLUSH WITH WATER,
THEN WATER CONTAINING SODIUM BICARBONATE. ORAL:DO NOT INDUCE VOMITING. IF
CONSCIOUS, DRINK LARGE AMOUNT OF WATER, FOLLOW WITH MILK OF MAGNESIA,
BEATEN EGGS OR VEGETABLE OIL.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: CAROLINA BIOGOLICAL SUPPLY CO
Label Street: 2700 YORK RD
Label City: BURLINGTON
Label State: NC
Label Zip Code: 27215-3387
Label Country: US
Label Emergency Number: 800-227-1150\910-584-0381(OUT SIDE)